不飽和二塩基酸誘導体の重合に関する研究 (第2報) マレイン酸およびフマル酸のメチルピニルエステルの合成,重合について

機関リポジトリ

書誌事項

タイトル別名
  • Polymerizations of U nsaturated Dibasic Acid Derivatives (II)Synthesis and Polymerizations of Methylvinylmaleate and fumarate

抄録

Methylvinylmaleate and fumarate were synthesized by Vinyl Interchange Reaction of vinylacetate with monomethylmaleate or fumarate and their physical properties were determined The cyclization polymerizations of above monomers with radical initiator were studied and the initial rate of polymerization of fumarate was about thirtytimes as large as that of maleate Residual double bond in polymers and infrared spectra of polymers indicated the formation of 5-membered lactone ring in both polymers and 4-membered lactone ring in polymaleate. The difference of percent cyclization between two polymers was discussed.

収録刊行物

詳細情報 詳細情報について

  • CRID
    1050564287741422080
  • NII論文ID
    120003989137
  • Web Site
    http://hdl.handle.net/10098/5090
  • 本文言語コード
    ja
  • 資料種別
    departmental bulletin paper
  • データソース種別
    • IRDB
    • CiNii Articles

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