Planar and Bent BN-Embedded p-Quinodimethanes Synthesized by Transmetalation of Bis(trimethylsilyl)-1,4-dihydropyrazines with Chloroborane

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  • Planar and Bent BN-Embedded <i>p</i>-Quinodimethanes Synthesized by Transmetalation of Bis(trimethylsilyl)-1,4-dihydropyrazines with Chloroborane

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Two BN-embedded p-quinodimethane derivatives were synthesized by a reaction of bis(trimethylsilyl)-1,4-dihydropyrazines, which are known as inorganic-salt-free reductants, with 9-chloro-9-borafluorene. The planar or bent structures of the resulting π-conjugated compounds were revealed by X-ray diffraction analysis. Their photophysical properties relate to their planar or bent structures due to the difference in the distribution of the HOMO.

Journal

  • Organometallics

    Organometallics 37 (12), 1833-1836, 2018-06-25

    ACS Publications

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