Synthesis of Azulene-Substituted Tetraarylpyrroles by Reaction of 1-Azulenyl Ketones with Benzoin and Ammonium Acetate

書誌事項

公開日
2017-10
資源種別
journal article
権利情報
  • © 2017 The Japan Institute of Heterocyclic Chemistry
DOI
  • 10.3987/com-17-13781
公開者
PERGAMON-ELSEVIER SCIENCE LTD

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説明

Tetraarylpyrroles with a 1-azulenyl substituent were prepared by the reaction of 1-azulenyl ketones, which have various aryl-substituents at their alpha-position, with benzoin in the presence of ammonium acetate as a nitrogen source of the pyrrole ring. Optical property of the tetraarylpyrroles obtained by the reaction was clarified by UV/Vis spectroscopy and/or time-dependent density functional theory (TD-DFT) calculations.

収録刊行物

  • HETEROCYCLES

    HETEROCYCLES 94 (10), 1870-1883, 2017-10

    PERGAMON-ELSEVIER SCIENCE LTD

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