Magnetic Studies on Eu3MO7 (M = Nb, Ta, Ir) with Fluorite-related Structure by 151Eu Mössbauer Spectroscopy and Magnetic Susceptibility Measurements

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  • Magnetic Studies on Eu3MO7 (M = Nb, Ta, Ir) with Fluorite-related Structure by Eu-151 Mossbauer Spectroscopy and Magnetic Susceptibility Measurements

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Magnetic properties of europium-containing compounds Eu3MO7 (M = Nb, Ta, Ir) with fluorite-related structure have been investigated. Magnetic susceptibility measurements show that all these compounds are paramagnetic and have no magnetic ordering down to 1.8 K. At very low temperatures (T < 50 K), the susceptibilities of each compound attain constant values, which is characteristic of the ground state for Eu3+ ions. The results of Eu-151 Mossbauer spectroscopic measurements show that the asymmetric parameter for Eu(2) in seven-coordination is much larger than that for Eu(1) in cubic environment, which in accordance with the crystallographic result.

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