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3,3-Dibromo-2-trifluoromethyl acrylic acid ethyl ester: a versatile platform for the stereoselective preparation of functionalized-α-trifluoromethyl α,β-unsaturated lactones and trifluoromethyl pyrazolinones
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Description
We herein describe a method for synthetic routes to multi-functionalized-α-trifluoromethyl α,β-unsaturated lactones and trifluoromethyl pyrazolinones. This involves a tandem stereoselective functionalization of 3,3-dibromo-2-trifluoromethyl acrylic acid ethyl ester and intramolecular cyclization reaction to afford precursors for a Suzuki-Miyaura cross-coupling reaction with arylboronic acids.
Journal
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- Organic Chemistry Frontiers
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Organic Chemistry Frontiers 3 (12), 1661-1667, 2016-12
Royal Society of Chemistry
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Details 詳細情報について
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- CRID
- 1050568772217183872
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- NII Article ID
- 120006987602
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- ISSN
- 20524129
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- HANDLE
- 10069/37368
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- Text Lang
- en
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- Article Type
- journal article
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- Data Source
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- IRDB
- Crossref
- CiNii Articles
- KAKEN
- OpenAIRE