Boronyl-Group-Assisted Decatungstate-Catalyzed Benzylic C(sp^3)–H Alkylation

IR (HANDLE) Open Access
  • Jiang, Hui
    Department of Interdisciplinary Engineering Sciences, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
  • Torigoe, Takeru
    Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology
  • Kuninobu, Yoichiro
    Department of Interdisciplinary Engineering Sciences, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University Institute for Materials Chemistry and Engineering, Kyushu University

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Description

Boronic acid synthesis primarily involves the introduction of boronyl groups. However, an alternative route that involves the functionalization of boronic acids has not received much attention. This study describes the catalytic C(sp^3)–H alkylation of ortho-tolylboronic acids utilizing the interaction between a free boronyl group [−B(OH)_2] and a decatungstate photocatalyst [W_<10>O_<32>]^<4–>. The boronyl groups of the alkylated products could be converted without isolation of the alkylated product.

Journal

  • Organic Letters

    Organic Letters 26 (23), 4853-4856, 2024-06-05

    American Chemical Society (ACS)

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Details 詳細情報について

  • CRID
    1050585946603079552
  • NII Book ID
    AA11347843
  • ISSN
    15237052
    15237060
  • HANDLE
    2324/7344072
  • Text Lang
    en
  • Article Type
    journal article
  • Data Source
    • IRDB

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