Boronyl-Group-Assisted Decatungstate-Catalyzed Benzylic C(sp^3)–H Alkylation

DOI IR (HANDLE) Open Access
  • Jiang, Hui
    Department of Interdisciplinary Engineering Sciences, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University
  • Torigoe, Takeru
    Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology
  • Kuninobu, Yoichiro
    Department of Interdisciplinary Engineering Sciences, Interdisciplinary Graduate School of Engineering Sciences, Kyushu University Institute for Materials Chemistry and Engineering, Kyushu University

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  • Boronyl-Group-Assisted Decatungstate-Catalyzed Benzylic C(sp<sup>3</sup>)–H Alkylation

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Description

Boronic acid synthesis primarily involves the introduction of boronyl groups. However, an alternative route that involves the functionalization of boronic acids has not received much attention. This study describes the catalytic C(sp^3)–H alkylation of ortho-tolylboronic acids utilizing the interaction between a free boronyl group [−B(OH)_2] and a decatungstate photocatalyst [W_<10>O_<32>]^<4–>. The boronyl groups of the alkylated products could be converted without isolation of the alkylated product.

Journal

  • Organic Letters

    Organic Letters 26 (23), 4853-4856, 2024-06-05

    American Chemical Society (ACS)

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