Pressure effects on an organic radical ferromagnet: 2,5-difluorophenyl-a-nitronyl nitroxide
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Raising a transition temperature (Tc) in organic radical ferromagnets is a desire for material scientists. We investigated the pressure effects on an organic radical ferromagnet 2,5-difluorophenyl-α-nitronyl nitroxide (2,5-DFPNN), which has a ferromagnetic transition at 0.45 K. The hydrostatic pressure effects were investigated through measurements of ac magnetic susceptibility (χ) up to P=1.7GPa, heat capacity (Cp) up to P=1.5GPa, and powder x-ray diffraction up to P=4.7GPa. Furthermore, ac magnetic susceptibility under nonhydrostatic pressure was also measured in the pressure region up to 10.0 GPa. As for 2,5-DFPNN, we observed the pressure-induced enhancement of Tc as dTc/dP=7.9×10−2K/GPa [Tc(P=1.5GPa)=0.57K], while other prototypes, the β phase of p-NPNN and p−Cl−C6H4−CH=N−TEMPO show the negative pressure effects. The results for the Cp and the crystal structural analysis suggest that the magnetic dimension of the short-range order developing above Tc transforms from one dimension (a axis) to two dimensions (ac plane) under high pressure. This increase of the magnetic dimension probably promotes to increase Tc. The ferromagnetic signal of χ, however, decreases with increasing pressure, and finally disappears for P>~5.0GPa. The decrease seems to originate from the decrease of the ferromagnetic interaction along the b axis. Similar instability of organic ferromagnetic long range order against pressure has been observed for the β phase of p-NPNN and p−Cl−C6H4−CH=N−TEMPO.
収録刊行物
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- Physical review. Third series. B, Condensed matter and materials physics
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Physical review. Third series. B, Condensed matter and materials physics 67 (2), 024427-1-024427-8, 2003-01-28
American Physical Society
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詳細情報 詳細情報について
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- CRID
- 1050845763839857280
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- NII論文ID
- 120002440811
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- NII書誌ID
- AA11187113
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- ISSN
- 24699969
- 10980121
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- HANDLE
- 10228/633
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- 本文言語コード
- en
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- 資料種別
- journal article
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- データソース種別
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- IRDB
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