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Catalytic Asymmetric Synthesis of 2,6‐Disubstituted Cuneanes via Enantioselective Constitutional Isomerization of 1,4‐Disubstituted Cubanes
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- Takebe, Hiyori
- Kyoto University Faculty of Engineering Graduate School of Engineering (Kyoto Daigaku Kogakubu Daigakuin Kogaku Kenkyuka)
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- Matsubara, Seijiro
- Kyoto University Faculty of Engineering Graduate School of Engineering (Kyoto Daigaku Kogakubu Daigakuin Kogaku Kenkyuka)
Bibliographic Information
- Other Title
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- Catalytic Asymmetric Synthesis of 2,6‐Disubstituted Cuneanes through Enantioselective Constitutional Isomerization of 1,4‐Disubstituted Cubanes
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Description
2, 6-Disubstituted cuneane has potential as a p -disubstituted benzene bioisostere and a novel chiral scaffold. It is a constitutional isomer of a 1, 4-disubstituted cubane obtained via a metal-catalyzed skeletal rearrangement. Unlike the highly symmetrical 1, 4-disubstituted cubane, the isomerized 2, 6-disubstituted cuneane is a chiral molecule possessing C 2 symmetry. Examining various chiral catalysts revealed that the Pd-pincer catalyst provides a good asymmetric induction.
Journal
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- European Journal of Organic Chemistry
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European Journal of Organic Chemistry 2022 (37), e202200567-, 2022-10-07
Wiley
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Details 詳細情報について
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- CRID
- 1050856660844282880
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- ISSN
- 10990690
- 1434193X
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- HANDLE
- 2433/276586
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- Text Lang
- en
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- Article Type
- journal article
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- Data Source
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- IRDB
- Crossref
- KAKEN
- OpenAIRE