Hydrogen desorption and cracking associated with martensitic transformation in Fe-Cr-Ni-Based austenitic steels with different carbon contents

書誌事項

公開日
2017-10
資源種別
journal article
権利情報
  • https://www.elsevier.com/tdm/userlicense/1.0/
  • https://www.elsevier.com/legal/tdmrep-license
  • http://www.elsevier.com/open-access/userlicense/1.0/
DOI
  • 10.1016/j.ijhydene.2017.08.209
公開者
Elsevier BV

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説明

Abstract The hydrogen embrittlement behavior of Fe-19Cr-8Ni-0.05C and Fe-19Cr-8Ni-0.14C metastable austenitic steels was investigated using tensile tests under hydrogen-charging, cryogenic thermal desorption spectroscopy, and in situ deformation experiments. Coupled with post-mortem microstructure characterization, the cracking paths were clarified to be transgranular along {110}α and {100}α in the Fe-19Cr-8Ni-0.05C steel and {100}α in the Fe-19Cr-8Ni-0.14C steel. Intergranular cracking also occurred in the Fe-19Cr-8Ni-0.05C steel when α′-martensite thoroughly covered the grain boundaries. Occurrence of the transgranular and intergranular hydrogen-assisted cracking in the steels is assisted by (1) an increase in the hydrogen-affected zone associated with presence of thermally induced α′-martensite, and (2) an increase in the local mobility of hydrogen that occurs with the deformation-induced α′-martensitic transformation. Additionally, (3) the transgranular hydrogen-assisted cracking is assisted by the intersection of deformation bands driven by the maximum Schmid factor and the stress concentration at the crack tip.

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