(<i>Z</i>)-Selective Hydrosilylation of Terminal Alkynes with HSiMe(OSiMe<sub>3</sub>)<sub>2</sub> Catalyzed by a Ruthenium Complex Containing an N-Heterocyclic Carbene

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  • Yuichiro Mutoh
    Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan
  • Yusei Mohara
    Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan
  • Shinichi Saito
    Department of Chemistry, Faculty of Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan

書誌事項

公開日
2017-09-08
資源種別
journal article
権利情報
  • http://pubs.acs.org/page/policy/authorchoice_termsofuse.html
DOI
  • 10.1021/acs.orglett.7b02477
公開者
American Chemical Society (ACS)

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説明

The N-heterocyclic-carbene-ligated ruthenium complex [RuHCl(CO)(H2IMes)(PCy3)] exhibits high catalytic activity for the (Z)-selective hydrosilylation of various terminal alkynes with 1,1,1,3,5,5,5-heptamethyltrisiloxane (HSiMe(OSiMe3)2). The stereoretentive derivatization of the (Z)-alkenylsiloxanes allows the synthesis of biologically active compounds, e.g. potent antitumor agents and inhibitors for induced-NO synthase.

収録刊行物

  • Organic Letters

    Organic Letters 19 (19), 5204-5207, 2017-09-08

    American Chemical Society (ACS)

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