Redox Active Cation Intercalation/Deintercalation in Two-Dimensional Layered MnO<sub>2</sub> Nanostructures for High-Rate Electrochemical Energy Storage
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- Pan Xiong
- International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan
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- Renzhi Ma
- International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan
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- Nobuyuki Sakai
- International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan
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- Xueyin Bai
- International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan
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- Shen Li
- Department of Materials Science & Engineering, Royal Institute of Technology, SE-100 44 Stockholm, Sweden
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- Takayoshi Sasaki
- International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan
書誌事項
- 公開日
- 2017-02-08
- 資源種別
- journal article
- DOI
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- 10.1021/acsami.6b14612
- 公開者
- American Chemical Society (ACS)
この論文をさがす
説明
Two-dimensional (2D) layered materials with a high intercalation pseudocapacitance have long been investigated for Li+-ion-based electrochemical energy storage. By contrast, the exploration of guest ions other than Li+ has been limited, although promising. The present study investigates intercalation/deintercalation behaviors of various metal ions in 2D layered MnO2 with various interlayer distances, K-birnessite nanobelt (K-MnO2), its protonated form (H-MnO2), and a freeze-dried sample of exfoliated nanosheets. Series of metal ions, such as monovalent Li+, Na+, and K+ and divalent Mg2+, exhibit reversible intercalation during charge/discharge cycling, delivering high-rate pseudocapacitances. In particular, the freeze-dried MnO2 of exfoliated nanosheets restacked with the largest interlayer spacing and a less compact 3D network exhibits the best rate capability and a stable cyclability over 5000 cycles. Both theoretical calculation and kinetic analysis reveal that the increased interlayer distance facilitates the fast diffusion of cations in layered MnO2 hosts. The results presented herein provide a basis for the controllable synthesis of layered nanostructures for high-rate electrochemical energy storage using various single- and multivalent ions.
収録刊行物
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- ACS Applied Materials & Interfaces
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ACS Applied Materials & Interfaces 9 (7), 6282-6291, 2017-02-08
American Chemical Society (ACS)