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- Dharmesh Varade
- Material Chemistry Laboratory, Kawamura Institute of Chemical Research, 631 Sakado, Sakura, Chiba 285-0078, Japan
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- Hideki Abe
- National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
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- Yusuke Yamauchi
- National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
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- Kazutoshi Haraguchi
- Material Chemistry Laboratory, Kawamura Institute of Chemical Research, 631 Sakado, Sakura, Chiba 285-0078, Japan
書誌事項
- 公開日
- 2013-11-05
- 資源種別
- journal article
- DOI
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- 10.1021/am402998q
- 公開者
- American Chemical Society (ACS)
この論文をさがす
説明
Nanostructured novel Pt/Clay nanocomposites consisting of well-defined Pt nanoparticles prepared by clay-mediated in situ reduction displays very high thermal stability, large BET surface area and superior catalytic activity for CO oxidation as compared to a model reference Pt/SiO2 catalysts. CO oxidation has attracted renewed attention because of its technological importance in the area of pollution control. The Pt/Clay system consisting of Pt nanoparticles strongly immobilized between the atomic layers of clay inhibits nanoparticle sintering and loss of catalytic activity even after prolonged heating at high temperatures. At elevated temperatures (300 °C), the Pt/Clay system demonstrates significant enhancement of catalytic activity, with almost 100% CO conversion in less than 5 min. Emphasis is given to the role played by the clay supporting material which is chemically and thermally stable under the catalytic conditions of exhaust purification.
収録刊行物
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- ACS Applied Materials & Interfaces
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ACS Applied Materials & Interfaces 5 (22), 11613-11617, 2013-11-05
American Chemical Society (ACS)
