Reversible Emergence of a Self-Assembled Layered Structure From Three-Dimensional Isotropic Ionic Crystal of a Cluster Compound (4-HNC<sub>5</sub>H<sub>4</sub>OH)<sub>2</sub>Mo<sub>6</sub>Cl<sub>14</sub> Driven By Absorption of Water and Alcohols

  • Kei Inumaru
    Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1, Kagamiyama, Higashi-Hiroshima 739-8527, Japan
  • Takashi Kikudome
    Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1, Kagamiyama, Higashi-Hiroshima 739-8527, Japan
  • Hiroshi Fukuoka
    Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1, Kagamiyama, Higashi-Hiroshima 739-8527, Japan
  • Shoji Yamanaka
    Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1, Kagamiyama, Higashi-Hiroshima 739-8527, Japan

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Description

The compound comprising nanometer scale cluster molecules showed unusual reversible structural transformation between an isotropic ionic crystal and a layered structure of which the interlayer spaces are filled with the absorbed molecules.

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