Synergistic Catalysis of Ionic Brønsted Acid and Photosensitizer for a Redox Neutral Asymmetric α-Coupling of <i>N</i>-Arylaminomethanes with Aldimines
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- Daisuke Uraguchi
- Institute of Transformative Bio-Molecules (WPI-ITbM) and Department of Applied Chemistry, Graduate School of Engineering and ‡CREST, Japan Science and Technology Agency (JST), Nagoya University, Nagoya 464-8602, Japan
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- Natsuko Kinoshita
- Institute of Transformative Bio-Molecules (WPI-ITbM) and Department of Applied Chemistry, Graduate School of Engineering and ‡CREST, Japan Science and Technology Agency (JST), Nagoya University, Nagoya 464-8602, Japan
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- Tomohito Kizu
- Institute of Transformative Bio-Molecules (WPI-ITbM) and Department of Applied Chemistry, Graduate School of Engineering and ‡CREST, Japan Science and Technology Agency (JST), Nagoya University, Nagoya 464-8602, Japan
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- Takashi Ooi
- Institute of Transformative Bio-Molecules (WPI-ITbM) and Department of Applied Chemistry, Graduate School of Engineering and ‡CREST, Japan Science and Technology Agency (JST), Nagoya University, Nagoya 464-8602, Japan
書誌事項
- 公開日
- 2015-10-16
- 資源種別
- journal article
- DOI
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- 10.1021/jacs.5b09329
- 10.1002/chin.201617085
- 公開者
- American Chemical Society (ACS)
この論文をさがす
説明
A redox neutral, highly enantioselective coupling between N-arylaminomethanes and N-sulfonyl aldimines was developed by harnessing the efficient catalysis of P-spiro chiral arylaminophosphonium barfate and a transition-metal photosensitizer under visible light irradiation. This mode of synergistic catalysis provides a powerful strategy for controlling the bond-forming processes of reactive radical intermediates.
収録刊行物
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- Journal of the American Chemical Society
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Journal of the American Chemical Society 137 (43), 13768-13771, 2015-10-16
American Chemical Society (ACS)