Raman Characterization of ABA- and ABC-Stacked Trilayer Graphene

  • Chunxiao Cong
    Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore
  • Ting Yu
    Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore
  • Kentaro Sato
    Department of Physics, Tohoku University, Sendai, Miyagi 9808578 Japan
  • Jingzhi Shang
    Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore
  • Riichiro Saito
    Department of Physics, Tohoku University, Sendai, Miyagi 9808578 Japan

書誌事項

公開日
2011-10-11
資源種別
journal article
DOI
  • 10.1021/nn203472f
公開者
American Chemical Society (ACS)

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説明

Bernal (ABA stacking order) and rhombohedral (ABC) trilayer graphene (3LG) are characterized by Raman spectroscopy. From a systematic experimental and theoretical analysis of the Raman modes in both of these 3LGs, we show that the G band, G' (2D) band, and the intermediate-frequency combination modes of 3LGs are sensitive to the stacking order of 3LG. The phonon wavevector q, that gives the double resonance Raman spectra is larger in ABC than ABA, which is the reason why we get the different Raman frequencies and their spectral widths for ABA and ABC 3LG. The weak electron-phonon interaction in ABC-stacked 3LG and the localized strain at the boundary between ABC- and ABA-stacked domains are clearly reflected by the softening of the G mode and the G' mode, respectively.

収録刊行物

  • ACS Nano

    ACS Nano 5 (11), 8760-8768, 2011-10-11

    American Chemical Society (ACS)

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