Structures and Electrical Properties of (BTM-TS-TTP)4PF6

  • Misaki Yasuda
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Emiko Fujiwara
    Academic Frontier Promotion Center, Osaka Electro-Communication University
  • Shuji Aonuma
    Academic Frontier Promotion Center, Osaka Electro-Communication University
  • Hideki Fujiwara
    Department of Chemistry, Graduate School of Science, Osaka Prefecture University
  • Toyonari Sugimoto
    Department of Chemistry, Graduate School of Science, Osaka Prefecture University
  • Takashi Nakayashiki
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University
  • Kazuyoshi Tanaka
    Department of Molecular Engineering, Graduate School of Engineering, Kyoto University
  • Kazuyuki Takahashi
    Institute for Molecular Science
  • Hayao Kobayashi
    Institute for Molecular Science
  • Yohji Misaki
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University

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<jats:title>Abstract</jats:title> <jats:p>(BTM-TS-TTP)4PF6, where BTM-TS-TTP is 2-[4,5-bis(methylthio)-1,3-dithiol-2-ylidene]-5-(1,3-diselenol-2-ylidene)-1,3,4,6-tetrathiapentalene, has been prepared. An X-ray structure analysis reveals that it has a λ-type array of the donors. It exhibited metallic conducting behavior down to 5 K.</jats:p>

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