A CNDO Study of Biphenyl

  • Akio Tajiri
    The Chemical Research Institute of Non-aqueous Solutions, Tohoku University
  • Shohji Takagi
    The Chemical Research Institute of Non-aqueous Solutions, Tohoku University
  • Masahiro Hatano
    The Chemical Research Institute of Non-aqueous Solutions, Tohoku University

書誌事項

公開日
1973-04-01
権利情報
  • https://academic.oup.com/pages/standard-publication-reuse-rights
DOI
  • 10.1246/bcsj.46.1067
公開者
Oxford University Press (OUP)

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説明

<jats:title>Abstract</jats:title> <jats:p>The ground-state electronic structure of biphenyl were studied by the use of the CNDO/2 method. It was found that the lengthening of the central C–C bond in biphenyl gave a reasonable minimum point for the potential energy curve. A modified version of the CNDO/2 method was used in order to calculate the electronic spectra of biphenyl for three possible (planar, angular, and vertical) conformations. The method gave a reasonable interpretation of the spectral features of biphenyl.</jats:p>

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