Electrochemical Fixation of Molecular Nitrogen on p-Type Gallium Phosphide Photocathode

DOI PDF 被引用文献2件 参考文献8件 オープンアクセス
  • Masashi Koizumi
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Hiroshi Yoneyama
    Department of Applied Chemistry, Faculty of Engineering, Osaka University
  • Hideo Tamura
    Department of Applied Chemistry, Faculty of Engineering, Osaka University

書誌事項

公開日
1981-06-01
権利情報
  • https://academic.oup.com/pages/standard-publication-reuse-rights
DOI
  • 10.1246/bcsj.54.1682
公開者
Oxford University Press (OUP)

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説明

<jats:title>Abstract</jats:title> <jats:p>Electrochemical fixation of molecular nitrogen to ammonia and hydrazine at p-type GaP photocathodes was studied in nonaqueous electrolytes containing either one of titanium tetraisopropoxide, titanium trichloride, vanadium trichloride, or chromium trichloride and a trace amount of water. Positive evidences for the nitrogen fixation were obtained in these electrolytes, but the current efficiency was quite low, and usually less than 1%. It is suggested from the present study that there are a variety of choices of electrolyte systems for the nitrogen fixation.</jats:p>

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