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- Yoshihisa Watanabe
- Department of Hydrocarbon Chemistry, Kyoto University
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- Tetsuo Ohta
- Department of Hydrocarbon Chemistry, Kyoto University
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- Yasushi Tsuji
- Department of Hydrocarbon Chemistry, Kyoto University
説明
<jats:title>Abstract</jats:title> <jats:p>Carbonyl compounds were hydrogenated to the corresponding alcohols in excellent yields using formic acid with a ruthenium complex at 125 °C for 3 h. 2-Propanone was reduced to 2-propanol by RuCl2(PPh3)3–HCOOH system in 94% yield with 98% selectivity. 3-Pentanone, cyclohexanone, acetophenone, and propiophenone were hydrogenated to the corresponding alcohols in 86, 78, 84, and 86% yields respectively. The ketone having the bulkier alkyl groups showed lower reactivity. The catalytic activity was found to decrease in the order RuCl2(PPh3)3, RuHCl(PPh3)3, RuHCl(CO)(PPh3)3, and RuH2(PPh3)4.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 55 (8), 2441-2444, 1982-08-01
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360002219101783680
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- NII論文ID
- 130001986080
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- ISSN
- 13480634
- 00092673
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- データソース種別
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