Synthesis and Properties of Novel [5]Radialenes Substituted with Multiple 1,3-Dithiol-2-yildenes

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  • Masafumi Ueda
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Yui Ogura
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Yohji Misaki
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University

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<jats:title>Abstract</jats:title> <jats:p>Novel [5]radialenes with four 1,3-dithiol-2-ylidene (DT) units (2) and ethylene analogs of [5]dendralene derivatives with five DT units (3) were synthesized. Cyclic voltammetry revealed that 2 exhibited two pairs of two-electron redox processes, whereas the bis(methylthio) derivative of 3 (3a) showed a simultaneous four-electron-transfer process.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 42 (5), 562-564, 2013-04-24

    Oxford University Press (OUP)

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