A Tris-fused Tetrathiafulvalene Extended with Cyclohexene-1,4-diylidene: A New Positive Electrode Material for Organic Rechargeable Batteries

DOI PDF 被引用文献26件 参考文献9件
  • Minami Kato
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Daisuke Ogi
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University
  • Masaru Yao
    Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology (AIST)
  • Yohji Misaki
    Department of Applied Chemistry, Graduate School of Science and Engineering, Ehime University

説明

<jats:title>Abstract</jats:title> <jats:p>Derivatives of tris-fused TTF donors 3 extended with cyclohexene-1,4-diylidene were synthesized. Cyclic voltammetry revealed that the tetrakis(hexylthio)-3 (3c) exhibited three stages of a two-electron redox process to afford the hexacation. The rechargeable battery incorporating tetrakis(methylsulfanyl)-3 (3b) as the positive electrode material exhibited a high cycle performance in spite of utilizing the highest oxidation state of +6.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 42 (12), 1556-1558, 2013-10-03

    Oxford University Press (OUP)

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