Unique Synthetic Approach toward a Phosphaalkene: Synthesis of a Selenium-substituted Phosphaalkene with Bulky Substituents
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- Koh Sugamata
- Institute for Chemical Research, Kyoto University
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- Takahiro Sasamori
- Institute for Chemical Research, Kyoto University
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- Norihiro Tokitoh
- Institute for Chemical Research, Kyoto University
Description
<jats:title>Abstract</jats:title> <jats:p>A selenium-substituted phosphaalkene, (Me3Si)2C=PSeTrp (1, Trp: 9-triptycyl), was synthesized by two methods, substitution reaction of (Me3Si)2C=PCl (3) with TrpSeLi, and treatment of TsiP(Cl)SeTrp (4, Tsi: C(SiMe3)3) with a catalytic amount of AlCl3. The newly obtained phosphaalkene was characterized in detail.</jats:p>
Journal
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- Chemistry Letters
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Chemistry Letters 43 (1), 95-96, 2013-10-09
Oxford University Press (OUP)
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Details 詳細情報について
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- CRID
- 1360002219105454208
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- NII Article ID
- 130004427087
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- ISSN
- 13480715
- 03667022
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- Data Source
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- Crossref
- CiNii Articles
- KAKEN