Synthesis, Structures, and Electrochemical Properties of New Extensively Conjugated TTF
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- Daisuke Ogi
- Department of Applied Chemistry, Graduate School of Engineering, Ehime University
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- Shuka Yoshimoto
- Department of Applied Chemistry, Graduate School of Engineering, Ehime University
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- Takashi Shirahata
- Department of Applied Chemistry, Graduate School of Engineering, Ehime University
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- Yohji Misaki
- Department of Applied Chemistry, Graduate School of Engineering, Ehime University
説明
<jats:title>Abstract</jats:title> <jats:p>Extensively conjugated tetrathiafulvalene (TTF) derivatives substituted with a TTF-fused 1,4-dithiafulven-6-yl group 4 have been synthesized. Theoretical calculation and X-ray crystal structure analysis of 4a demonstrated that the conformation A, in which the two TTF units are linearly oriented, is slightly more stable than the conformation B, which adopted orthogonal arrangement of two TTF units in the neutral state. Cyclic voltammetry revealed the presence of the intramolecular 1,5-S···S interaction that brings about the stabilization of the conformation B in the tricationic state.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 44 (4), 554-556, 2015-01-27
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360002219105641984
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- NII論文ID
- 130005062132
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- ISSN
- 13480715
- 03667022
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- 資料種別
- journal article
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