A NEW TYPE OF URUSHIBARA NICKEL CATALYST (U–Ni–N). ACTIVATION OF THE PRECIPITATED NICKEL (PRECURSOR OF URUSHIBARA NICKEL CATALYSTS) BY REFLUXING WITH ALCOHOLS

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  • Masatsugu Kajitani
    Department of Chemistry, Faculty of Science and Technology, Sophia University
  • Junko Okada
    Department of Chemistry, Faculty of Science and Technology, Sophia University
  • Tetsuya Ueda
    Department of Chemistry, Faculty of Science and Technology, Sophia University
  • Akira Sugimori
    Department of Chemistry, Faculty of Science and Technology, Sophia University
  • Yoshiyuki Urushibara
    Department of Chemistry, Faculty of Science and Technology, Sophia University

Abstract

<jats:title>Abstract</jats:title> <jats:p>A new method of activation of ppt-Ni by refluxing with alcohols is described. The ppt-Ni activated in this way (U–Ni–N) exhibits high catalytic activity corresponding to U–Ni–A. The catalyst performs selective reactions in the hycrogenation of 1-octene (low isomerization) and of cyclcolefins.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 2 (8), 777-780, 1973-08

    Oxford University Press (OUP)

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