Synthesis and Reactions of Organoplatinum Compounds of C60, C60Ptn

DOI PDF 被引用文献1件 参考文献9件
  • Hideo Nagashima
    Department of Materials Science, Toyohashi University of Technology
  • Yoshiyuki Kato
    Department of Materials Science, Toyohashi University of Technology
  • Hirofumi Yamaguchi
    Department of Materials Science, Toyohashi University of Technology
  • Eiji Kimura
    Department of Materials Science, Toyohashi University of Technology
  • Teruhiko Kawanishi
    Research Center for Chemometrics, Toyohashi University of Technology
  • Masanao Kato
    Research Center for Chemometrics, Toyohashi University of Technology
  • Yahachi Saito
    Department of Electrical and Electronic Engineering, Mie University
  • Masaaki Haga
    Department of Chemistry, Faculty of Education, Mie University
  • Kenji Itoh
    Department of Materials Science, Toyohashi University of Technology

書誌事項

公開日
1994-07-01
権利情報
  • https://academic.oup.com/pages/standard-publication-reuse-rights
DOI
  • 10.1246/cl.1994.1207
公開者
Oxford University Press (OUP)

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説明

<jats:title>Abstract</jats:title> <jats:p>The organoplatinum compound of C60, C60Ptn (n = 1–2), was prepared either by the reaction of C60 with Pt(dba)2 or by the thermal disproportionation of C60Ptn (n = ca. 1). The C60Ptn obtained catalyzed the hydrogenation of diphenylacetylene regardless of the platinum content. Cleavage of carbon-platinum bonds of C60Ptn (n = ca. 1) was accomplished by the reactions with phosphines or phosphites, which provided general access to (η2-C60)PtL2 [L = phosphines and phosphites].</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 23 (7), 1207-1210, 1994-07-01

    Oxford University Press (OUP)

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