Structures and Properties of (TMEO-ST-TTP)2AsF6

  • Yohji Misaki
    Department of Molecular Engineering, Graduate Scholl of Engineering, Kyoto UniversityYoshida, Kyoto
  • Masateru Taniguchi
    Department of Molecular Engineering, Graduate Scholl of Engineering, Kyoto UniversityYoshida, Kyoto
  • Kazuyoshi Tanaka
    Department of Molecular Engineering, Graduate Scholl of Engineering, Kyoto UniversityYoshida, Kyoto
  • Kazuo Takimiya
    Department of Applied Chemistry, Faculty of Engineering, Hiroshima UniversityHigashi-Hiroshima
  • Atsushi Morikami
    Department of Applied Chemistry, Faculty of Engineering, Hiroshima UniversityHigashi-Hiroshima
  • Tetsuo Otsubo
    Department of Applied Chemistry, Faculty of Engineering, Hiroshima UniversityHigashi-Hiroshima
  • Takehiko Mori
    Department of Organic and Polymeric Materials, Faculty of Engineering, Tokyo Insitute of TechnologyO-okayama, Tokyo

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Description

<jats:title>Abstract</jats:title> <jats:p>The title material, where TMEO-ST-TTP is 2-[4,5-bis(methylthio)-1,3-diselenol-2-ylidene)-5-(4,5-ethylendioxy-1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene, shows metallic conducting behavior down to 4.2 K. X-Ray structure analysis reveals it has the β-type array of donors in the BEDT-TTF salts. A tight-binding band calculation suggests the present salt has a quasi-one-dimensional Fermi surface.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 28 (9), 859-860, 1999-09-01

    Oxford University Press (OUP)

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