Synthesis and Structure of a New Reduced Isopolyvanadate, [V17O42]4−

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<jats:title>Abstract</jats:title> <jats:p>Reduced heptadecavanadate [V17O42]4− has been synthesized from [H3V10O28]3− by the reaction using palladium 1,5-COD complex, and characterized by a single crystal X-ray structure analysis. The structure can be regarded as a fused decavanadate and consists of an arrangement of thirteen edge shared VO6 octahedra and four VO5 square pyramids.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 29 (7), 770-771, 2000-07-01

    Oxford University Press (OUP)

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