Efficient Photocatalytic Oxidation of Cycloalkenes by Dihydroxo(tetraphenylporphyrinato)antimony Supported on Silica Gel under Visible Light Irradiation

DOI DOI PDF 被引用文献7件 参考文献6件
  • Tsutomu Shiragami
    Department of Applied Chemistry, Faculty of Engineering, University of Miyazaki
  • Ryu-ichi Makise
    Department of Applied Chemistry, Faculty of Engineering, University of Miyazaki
  • Yousuke Inokuchi
    Department of Applied Chemistry, Faculty of Engineering, University of Miyazaki
  • Jin Matsumoto
    Department of Applied Chemistry, Faculty of Engineering, University of Miyazaki
  • Haruo Inoue
    CREST, JST (Japan Science and Technology)
  • Masahide Yasuda
    Department of Applied Chemistry, Faculty of Engineering, University of Miyazaki

書誌事項

公開日
2004-05-24
権利情報
  • https://academic.oup.com/pages/standard-publication-reuse-rights
DOI
  • 10.1246/cl.2004.736
  • 10.1002/chin.200444113
公開者
Oxford University Press (OUP)

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説明

<jats:title>Abstract</jats:title> <jats:p>In order to develop a photocatalyst operating under visible light irradiation, silica gel-supported dihydroxo(tetraphenylporphyrinato)antimony (V) complex, [SbTPP(OH)2]+/SiO2, was prepared. The photocatalytic oxidation of cycloalkenes with oxygen molecule was performed on [SbTPP(OH)2]+/SiO2 particles under irradiation of fluorescent light. The photocatalytic oxidation of cycloalkenes gave the corresponding cis-1,2-epoxycycloalkane, 2-cycloalkene-1-ol, and trans-1,2-cycloalkanediol.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 33 (6), 736-737, 2004-05-24

    Oxford University Press (OUP)

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