X-ray Crystallographic Characterization of Potassium Pentaphenyl[60]fullerene

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  • Yutaka Matsuo
    Nakamura Functional Carbon Cluster Project, ERATO, Japan Science and Technology Agency
  • Kazukuni Tahara
    Department of Chemistry, The University of Tokyo
  • Eiichi Nakamura
    Nakamura Functional Carbon Cluster Project, ERATO, Japan Science and Technology Agency

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<jats:title>Abstract</jats:title> <jats:p>X-ray crystal structures of three differently solvated forms of potassium pentaphenyl[60]fullerene, K(C60Ph5)(thf)3, [K(thf)6][C60Ph5], and [K(18-crown-6)(dmf)][C60Ph5], indicate that the potassium cation and the fullerene cyclopentadienide become separated easily by cation solvation, and suggest that a solvent-separated ion pair is responsible for the formation of bilayer vesicles upon dissolution of KC60Ph5 in water.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 34 (8), 1078-1079, 2005-06-26

    Oxford University Press (OUP)

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