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Meso and Racemic Isomers of a New S-Bridged Diruthenium(II) Complex with Pendant Aminoalkyl Groups
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- Noriyuki Matsuura
- Department of Chemistry, Graduate School of Science, Osaka University
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- Asako Igashira-Kamiyama
- Department of Chemistry, Graduate School of Science, Osaka University
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- Tatsuya Kawamoto
- Department of Chemistry, Graduate School of Science, Osaka University
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- Takumi Konno
- Department of Chemistry, Graduate School of Science, Osaka University
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Description
<jats:title>Abstract</jats:title> <jats:p>A diruthenium(II) complex, [{Ru(bpy)2}2(μ-Haet)2]4+ ([1]4+, Haet = −SCH2CH2NH3+), which consists of two cis-[Ru(bpy)2]2+ units bridged by two thiolato groups, was newly prepared and separated into meso and racemic isomers. The spectroscopic and electrochemical properties of [1]4+, together with the crystal structure of its meso isomer, are reported.</jats:p>
Journal
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- Chemistry Letters
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Chemistry Letters 34 (9), 1252-1253, 2005-08-13
Oxford University Press (OUP)
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Details 詳細情報について
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- CRID
- 1360002219110574336
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- NII Article ID
- 130004722713
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- ISSN
- 13480715
- 03667022
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- Data Source
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- Crossref
- CiNii Articles
- OpenAIRE