A New Water-soluble and Acid-stable Dinuclear Organoiridium Dinitrate Complex

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  • Bunsho Kure
    Center for Future Chemistry, Kyushu University
  • Shunichi Fukuzumi
    Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University, SORST, JST
  • Seiji Ogo
    Center for Future Chemistry, Kyushu University

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<jats:title>Abstract</jats:title> <jats:p>A new water-soluble and acid-stable dinuclear organoiridium(III) dinitrate complex [{Cp∗Ir(NO3)}2(μ-Cl)2] (1, Cp∗ = η5-C5Me5) was synthesized by the reaction of a water-insoluble organoiridium(III) complex [(Cp∗IrCl)2(μ-Cl)2] (2) with two equivalents of AgBF4 in aqueous nitric acid (1 M HNO3/H2O) at 23 °C for 12 h. The structure of 1 with two monodentate NO3− ligands is discussed in comparison with structure of a mononuclear organoiridium(III) complex with one monodentate and one bidentate NO3− ligands, [Cp∗Ir(NO3)2] (3).</jats:p>

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  • Chemistry Letters

    Chemistry Letters 36 (12), 1468-1469, 2007-11-10

    Oxford University Press (OUP)

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