Palladium-catalyzed Carbon–Sulfur Cross-coupling Reactions of Aryl Chlorides with Indium Tris(organothiolates)

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  • Juntae Mo
    Department of Chemistry, College of Natural Sciences, Kangwon National University
  • Dahan Eom
    Department of Chemistry, College of Natural Sciences, Kangwon National University
  • Sung Hong Kim
    Analysis Research Division Daegu Center, Korea Basic Science Institute
  • Phil Ho Lee
    Department of Chemistry, College of Natural Sciences, Kangwon National University

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<jats:title>Abstract</jats:title> <jats:p>Pd-Catalyzed carbon–sulfur cross-coupling reactions of aryl chlorides with indium tris(organothiolates) were developed. Aryl chlorides reacted with indium tris(organothiolates) (0.35 equiv) in the presence of 4 mol % of Pd(OAc)2, 4.2 mol % of Xantphos, and Cs2CO3 as an additive, producing aryl–aryl and aryl–alkyl sulfides in good to excellent yields.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 40 (9), 980-982, 2011-09

    Oxford University Press (OUP)

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