Probing Absorption of Deuterium into Palladium Cathodes During D<sub>2</sub>O Electrolysis with an In Situ Electrochemical Microbalance Technique
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説明
<jats:p> The <jats:italic>in situ</jats:italic> observation of the absorption of deuterium (or hydrogen) into the Pd cathode during D<jats:sub>2</jats:sub>O (or H<jats:sub>2</jats:sub>O) electrolysis was made by an electrochemical microbalance technique which is based on the quartz-crystal electrode. The resonant frequency of the Pd-coated quartz-crystal electrode decreased with increasing amount of charge passed during electrolysis, and the frequency change for the D<jats:sub>2</jats:sub>O electrolysis was about twice that for the H<jats:sub>2</jats:sub>O electrolysis. The atom ratios of H/Pd and D/Pd of the H-Pd and D-Pd compounds resulting from the electrolysis were estimated to be 0.59 and 0.57, respectively. </jats:p>
収録刊行物
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- Japanese Journal of Applied Physics
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Japanese Journal of Applied Physics 29 (5A), L818-, 1990-05-01
IOP Publishing
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詳細情報 詳細情報について
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- CRID
- 1360003446840560768
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- NII論文ID
- 210000030043
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- ISSN
- 13474065
- 00214922
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- データソース種別
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