Individualized p‐Doped Carbon Nanohorns
-
- Anastasios Stergiou
- Theoretical and Physical Chemistry Institute National Hellenic Research Foundation 48 Vassileos Constantinou Avenue Athens 11635 Greece
-
- Zheng Liu
- Inorganic Functional Materials Research Institute National Institute of Advanced Industrial Science and Technology (AIST) Anagahora 2266-98, Shimoshidami, Moriyamaku Nagoya 463-8560 Japan
-
- Bin Xu
- Department of Electronic Engineering Tohoku University 6-6-05 Aoba, Aramaki, Aoba-Ku Sendai 980-8579 Japan
-
- Toshiro Kaneko
- Department of Electronic Engineering Tohoku University 6-6-05 Aoba, Aramaki, Aoba-Ku Sendai 980-8579 Japan
-
- Christopher P. Ewels
- Institut des Materiaux Jean Rouxel, CNRS Universite de Nantes 2 Rue de la Houssiniere, BP32229 44322 Nantes France
-
- Kazu Suenaga
- Nanomaterials Research Institute National Institute of Advanced Industrial Science and Technology (AIST) Central 5, 1-1-1 Higashi Tsukuba 305-8565 Japan
-
- Minfang Zhang
- Nanomaterials Research Institute National Institute of Advanced Industrial Science and Technology (AIST) Central 5, 1-1-1 Higashi Tsukuba 305-8565 Japan
-
- Masako Yudasaka
- Nanomaterials Research Institute National Institute of Advanced Industrial Science and Technology (AIST) Central 5, 1-1-1 Higashi Tsukuba 305-8565 Japan
-
- Nikos Tagmatarchis
- Theoretical and Physical Chemistry Institute National Hellenic Research Foundation 48 Vassileos Constantinou Avenue Athens 11635 Greece
この論文をさがす
説明
<jats:title>Abstract</jats:title><jats:p>A facile approach to individualize spherically aggregated pristine carbon nanohorns (pr‐CNHs) was established. Specifically, we found that treatment of pr‐CNHs with chlorosulfonic acid generates positively charged polarized species, which disintegrate toward individualized carbon nanohorns (in‐CNHs). Interestingly, the isolated in‐CNHs were revealed to be p‐doped owing to the adsorption of chlorosulfonate units. The findings were confirmed by data derived from high‐resolution transmission electron microscopy imaging, Raman and ultraviolet photoemission spectroscopy, and additionally supported by theoretical calculations and thermogravimetry.</jats:p>
収録刊行物
-
- Angewandte Chemie International Edition
-
Angewandte Chemie International Edition 55 (35), 10468-10472, 2016-07-22
Wiley