Negatively Charged π‐Electronic Systems by Deprotonation of Hydroxy‐Substituted Dipyrrolyldiketone Boron Complexes
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- Yoshifumi Sasano
- Department of Applied Chemistry, College of Life Sciences Ritsumeikan University Kusatsu 525–8577 Japan
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- Nobuhiro Yasuda
- Research and Utilization Division Japan Synchrotron Radiation Research Institute Sayo 679–5198 Japan
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- Hiromitsu Maeda
- Department of Applied Chemistry, College of Life Sciences Ritsumeikan University Kusatsu 525–8577 Japan
書誌事項
- 公開日
- 2016-10-26
- 資源種別
- journal article
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/asia.201601205
- 公開者
- Wiley
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説明
<jats:title>Abstract</jats:title><jats:p>Boron complexes of <jats:italic>meso</jats:italic>‐hydroxy‐substituted dipyrrolyldiketones, as the precursors of negatively charged π‐electronic systems, were synthesized via the oxidative introduction of an acetoxy unit at the <jats:italic>meso</jats:italic> position of dipyrrolyldiketones and subsequent hydrolysis. The anionic site formed upon deprotonation was moderately stabilized by hydrogen‐bond‐donating pyrrole NH, generating non‐complexing anionic species.</jats:p>
収録刊行物
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- Chemistry – An Asian Journal
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Chemistry – An Asian Journal 11 (23), 3423-3429, 2016-10-26
Wiley