Synthesis and Characterization of 6,13‐Diamino‐Substituted Pentacenes
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- Akihiro Ito
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo-ku Kyoto 615-8510 Japan
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- Masashi Uebe
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo-ku Kyoto 615-8510 Japan
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- Kazuki Takahashi
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo-ku Kyoto 615-8510 Japan
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- Hiroshi Ishikawa
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo-ku Kyoto 615-8510 Japan
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- Daisuke Sakamaki
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo-ku Kyoto 615-8510 Japan
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- Hiroyasu Sato
- X-ray Research Laboratory Rigaku Corporation Matsubara-cho 3-9-12 Akishima Tokyo 196-8666 Japan
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- Takashi Matsumoto
- X-ray Research Laboratory Rigaku Corporation Matsubara-cho 3-9-12 Akishima Tokyo 196-8666 Japan
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- Kazuyoshi Tanaka
- Department of Molecular Engineering Graduate School of Engineering Kyoto University Nishikyo-ku Kyoto 615-8510 Japan
書誌事項
- 公開日
- 2016-01-08
- 資源種別
- journal article
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/chem.201503996
- 10.1002/chin.201614088
- 公開者
- Wiley
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説明
<jats:title>Abstract</jats:title><jats:p>A series of 6,13‐diamino‐substituted pentacenes <jats:bold>1 a</jats:bold>–<jats:bold>d</jats:bold> has been prepared and characterized as a new class of pentacene derivatives with strong donor ability and enhanced solubility in common organic solvents. The spectroelectrochemical and DFT studies revealed that the two‐electron oxidation process was accompanied by the substantial structural change into a butterfly‐like conformation of the pentacene moiety. More importantly, the extent of deformation from the planar pentacene moiety in the dications of 6,13‐diaminopentacene is tunable by varying the N‐substituents.</jats:p>
収録刊行物
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- Chemistry – A European Journal
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Chemistry – A European Journal 22 (6), 2165-2170, 2016-01-08
Wiley
