Peripheral Modifications of <i>meso</i>‐Hydroxyporphyrins: Formation of π‐Electronic Anions and Ion‐Pairing Assemblies
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- Yoshifumi Sasano
- Department of Applied Chemistry, College of Life Sciences Ritsumeikan University Kusatsu 525-8577 Japan
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- Yohei Haketa
- Department of Applied Chemistry, College of Life Sciences Ritsumeikan University Kusatsu 525-8577 Japan
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- Hiroki Tanaka
- Department of Applied Chemistry, College of Life Sciences Ritsumeikan University Kusatsu 525-8577 Japan
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- Nobuhiro Yasuda
- Research and Utilization Division Japan Synchrotron Radiation Research Institute Sayo 679-5198 Japan
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- Ichiro Hisaki
- Green Nanotechnology Research Center, Research Institute for Electronic Science Hokkaido University Sapporo 001-0020 Japan
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- Hiromitsu Maeda
- Department of Applied Chemistry, College of Life Sciences Ritsumeikan University Kusatsu 525-8577 Japan
書誌事項
- 公開日
- 2019-04-25
- 資源種別
- journal article
- 権利情報
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- http://onlinelibrary.wiley.com/termsAndConditions#vor
- DOI
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- 10.1002/chem.201901095
- 公開者
- Wiley
この論文をさがす
説明
<jats:title>Abstract</jats:title><jats:p>Phenyl groups were introduced at the β‐positions proximal to the <jats:italic>meso</jats:italic>‐hydroxy moiety in hydroxyporphyrin Ni<jats:sup>II</jats:sup> complexes by oxidized BINAP Pd<jats:sup>II</jats:sup> complexes. Ion‐pairing assemblies of deprotonated π‐electronic anions, anionic site of which was stabilized by the introduced phenyl moieties with a bulky cation, were formed. They showed charge‐by‐charge assemblies, assembly modes of which were modulated by the anionic building units.</jats:p>
収録刊行物
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- Chemistry – A European Journal
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Chemistry – A European Journal 25 (27), 6712-6717, 2019-04-25
Wiley