Reissert‐Type Acylation with Acylzirconocene Chloride Complexes

DOI DOI Web Site Web Site 被引用文献2件 参考文献65件

この論文をさがす

説明

<jats:title>Abstract</jats:title><jats:p>In the presence of ClCO<jats:sub>2</jats:sub>Et, the use of CuI in MeNO<jats:sub>2</jats:sub> efficiently catalyzed the Reissert‐type acylation of isoquinoline derivatives with acylzirconocene chlorides. In the reaction of quinolines with acylzirconocene chlorides, the choice of catalyst and solvent was crucial to the regioselective formation of adducts. The cationic Rh<jats:sup>I</jats:sup>‐catalyzed reaction in MeNO<jats:sub>2</jats:sub> preferentially afforded 1,2 adducts. On the other hand, the Cu<jats:sup>I</jats:sup>‐catalyzed reaction in CH<jats:sub>2</jats:sub>Cl<jats:sub>2</jats:sub> preferentially afforded 1,4 adducts.</jats:p>

収録刊行物

被引用文献 (2)*注記

もっと見る

参考文献 (65)*注記

もっと見る

関連プロジェクト

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ