Formal C–H‐Azidation – Based Shortcut to Diazido Building Blocks for the Versatile Preparation of Photoaffinity Labeling Probes

DOI DOI Web Site Web Site 被引用文献21件 参考文献61件

書誌事項

公開日
2014-05-28
資源種別
journal article
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/ejoc.201402516
  • 10.1002/chin.201507088
公開者
Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>Short synthetic routes to diazido building blocks with different connectable groups were established on the basis of the sequential iridium‐catalyzed C–H borylation and copper‐catalyzed azidation of 1,3‐disubstituted benzenes, followed by diverse azido‐friendly functional‐group transformations. These building blocks facilitate the rapid development of effective diazido photoaffinity labeling probes that are useful for the identification of unknown target biomolecules of bioactive compounds.</jats:p>

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