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Stereoselective construction of all-carbon quaternary stereocenters by allylboration of chiral aldehydes: synthesis of a fragment of (+)-vibsanin A
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Description
Abstract Stereoselective construction of all-carbon quaternary stereocenters by allylboration of chiral aldehydes is described. Sugar-derived aldehydes were allylated with geranylboronate or nerylboronate to provide γ-adducts possessing quaternary stereocenters with high diastereoselectivity. The reaction was applied to the synthesis of a fragment of (+)-vibsanin A.
Journal
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- Tetrahedron
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Tetrahedron 72 (35), 5465-5471, 2016-09
Elsevier BV
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Details 詳細情報について
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- CRID
- 1360004232525395456
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- ISSN
- 00404020
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- Article Type
- journal article
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- Data Source
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- Crossref
- KAKEN
- OpenAIRE