Stereoselective construction of all-carbon quaternary stereocenters by allylboration of chiral aldehydes: synthesis of a fragment of (+)-vibsanin A

DOI Web Site Web Site 被引用文献2件 参考文献56件

書誌事項

公開日
2016-09
資源種別
journal article
権利情報
  • https://www.elsevier.com/tdm/userlicense/1.0/
DOI
  • 10.1016/j.tet.2016.07.030
公開者
Elsevier BV

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説明

Abstract Stereoselective construction of all-carbon quaternary stereocenters by allylboration of chiral aldehydes is described. Sugar-derived aldehydes were allylated with geranylboronate or nerylboronate to provide γ-adducts possessing quaternary stereocenters with high diastereoselectivity. The reaction was applied to the synthesis of a fragment of (+)-vibsanin A.

収録刊行物

  • Tetrahedron

    Tetrahedron 72 (35), 5465-5471, 2016-09

    Elsevier BV

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参考文献 (56)*注記

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