Synthesis of Pincer Iridium Complexes Bearing a Boron Atom and <sup><i>i</i></sup>Pr-Substituted Phosphorus Atoms: Application to Catalytic Transfer Dehydrogenation of Alkanes

DOI Web Site 研究データあり 被引用文献18件 参考文献35件
  • Keita Tanoue
    Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, 112-8551 Tokyo, Japan
  • Makoto Yamashita
    Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, 112-8551 Tokyo, Japan

書誌事項

公開日
2015-08-13
資源種別
journal article
DOI
  • 10.1021/acs.organomet.5b00376
公開者
American Chemical Society (ACS)

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説明

An iPr-substituted PBP-pincer ligand was synthesized and introduced to iridium metal to give iPr-(PBP)Ir(H)Cl and iPr-(PBP)Ir(C2H4) complexes. Both of these complexes were found to be moderately active for the catalytic transfer dehydrogenation of cyclooctane.

収録刊行物

  • Organometallics

    Organometallics 34 (16), 4011-4017, 2015-08-13

    American Chemical Society (ACS)

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