Design and Synthesis of Tunable Ligands with 4,4′-Bipyridyl as an Electron-Accepting Unit and Their Rhenium Complexes

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  • Takuto Kamatsuka
    Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan
  • Hiroshi Shinokubo
    Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan
  • Yoshihiro Miyake
    Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan

書誌事項

公開日
2017-08-24
資源種別
journal article
DOI
  • 10.1021/acs.organomet.7b00611
公開者
American Chemical Society (ACS)

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説明

We have designed and prepared a series of rhenium complexes with 4,4′-bipyridyl as an electron-accepting unit. Electrochemical studies revealed that oxidation and reduction of these complexes occurred on the rhenium center and the 4,4′-bipyridyl skeleton, respectively. The redox potentials of the rhenium complexes are controllable by tuning the substituents on the 4,4′-bipyridyl skeleton and the coordinating groups to the rhenium center. We have also examined the reactivity of the rhenium complexes in electrochemical and photochemical CO2 reduction.

収録刊行物

  • Organometallics

    Organometallics 36 (17), 3429-3434, 2017-08-24

    American Chemical Society (ACS)

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