Asymmetric Transformations under Iridium/Chiral Diene Catalysis

  • Midori Nagamoto
    Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan
  • Takahiro Nishimura
    Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan

書誌事項

公開日
2016-12-23
資源種別
journal article
DOI
  • 10.1021/acscatal.6b02495
公開者
American Chemical Society (ACS)

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説明

Chelating chiral dienes have become steering ligands for iridium in several types of asymmetric reactions. Some effective examples realized only by use of chiral diene ligands instead of conventional ligands based on phosphine and nitrogen have appeared in the iridium-catalyzed processes. In particular, it should be noted that Ir/chiral diene catalysts allow enantioselective reactions involving C–H bond activation. In this Perspective, recent progress in asymmetric reactions catalyzed by Ir/chiral diene complexes is summarized.

収録刊行物

  • ACS Catalysis

    ACS Catalysis 7 (1), 833-847, 2016-12-23

    American Chemical Society (ACS)

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