Rhodium(I)-Catalyzed C8-Alkylation of 1-Naphthylamide Derivatives with Alkenes through a Bidentate Picolinamide Chelation System
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- Supriya Rej
- Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
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- Naoto Chatani
- Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan
書誌事項
- 公開日
- 2018-06-18
- 資源種別
- journal article
- DOI
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- 10.1021/acscatal.8b01675
- 公開者
- American Chemical Society (ACS)
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説明
The rhodium(I)-catalyzed C–H alkylation of 1-naphthylamide derivatives with alkenes at the C8-position using a picolinamide directing group is reported. Various alkenes including styrene derivatives, α,β-unsaturated carbonyl compounds, and even unactivated alkene could also be used as coupling partners. The reaction mechanism was investigated in kinetic studies, deuterium labeling studies, and control experiments. The reaction appears to proceed through a rhodium carbene intermediate, which is generated from an alkene.
収録刊行物
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- ACS Catalysis
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ACS Catalysis 8 (7), 6699-6706, 2018-06-18
American Chemical Society (ACS)
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詳細情報 詳細情報について
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- CRID
- 1360004233149334784
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- ISSN
- 21555435
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- 資料種別
- journal article
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- データソース種別
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- Crossref
- KAKEN
- OpenAIRE
