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- Hiroki Sato
- Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Ibaraki 305-8571, Japan
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- Lisa Miya
- Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Ibaraki 305-8571, Japan
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- Kiyotaka Mitsumoto
- Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Ibaraki 305-8571, Japan
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- Takuto Matsumoto
- Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Ibaraki 305-8571, Japan
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- Takuya Shiga
- Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Ibaraki 305-8571, Japan
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- Graham N. Newton
- Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Ibaraki 305-8571, Japan
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- Hiroki Oshio
- Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Ibaraki 305-8571, Japan
書誌事項
- 公開日
- 2013-08-09
- 資源種別
- journal article
- DOI
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- 10.1021/ic401445u
- 公開者
- American Chemical Society (ACS)
この論文をさがす
説明
A nonanuclear copper grid complex, [Cu(II)9(L)6](BF4)6·1-PrOH·5H2O (1·1-PrOH·5H2O; L = 2,6-bis[5-(2-pyridinyl)-1H-pyrazol-3-yl]pyridine), was synthesized with a [3 × 3] grid structure consisting of nine Cu(II) ions and six deprotonated ligands and displayed four-step quasi-reversible redox behavior from [Cu(II)9] to [Cu(I)4Cu(II)5]. The corresponding heterovalent complex [Cu(I)2Cu(II)7(L)6](PF6)4·3H2O (2·3H2O) was successfully isolated and had a distorted core structure that radically changed the intramolecular magnetic coupling pathways.
収録刊行物
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- Inorganic Chemistry
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Inorganic Chemistry 52 (17), 9714-9716, 2013-08-09
American Chemical Society (ACS)