Geometric and Electronic Structure of Templated C<sub>60</sub> on Diindenoperylene Thin Films

  • A. Hinderhofer
    Institute for Applied Physics, University of Tübingen, Auf der Morgenstelle 10, 72076 Tübingen, Germany
  • A. Gerlach
    Institute for Applied Physics, University of Tübingen, Auf der Morgenstelle 10, 72076 Tübingen, Germany
  • K. Broch
    Institute for Applied Physics, University of Tübingen, Auf der Morgenstelle 10, 72076 Tübingen, Germany
  • T. Hosokai
    Department of Materials and Science, Iwate University, Ueda 4-3-5, Morioka, Iwate 020-8551, Japan
  • K. Yonezawa
    Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan
  • K. Kato
    Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan
  • S. Kera
    Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan
  • N. Ueno
    Graduate School of Advanced Integration Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan
  • F. Schreiber
    Institute for Applied Physics, University of Tübingen, Auf der Morgenstelle 10, 72076 Tübingen, Germany

書誌事項

公開日
2013-01-04
資源種別
journal article
DOI
  • 10.1021/jp3106056
公開者
American Chemical Society (ACS)

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説明

The structural order of C60 thin films is shown to be significantly improved by inserting a templating layer of diindenoperylene (DIP) between the SiO2 substrate and C60. In contrast to growth on an amorphous substrate like SiO2, C60 grown on DIP exhibits alignment of fcc-domains with the (111) plane parallel to the substrate and a significant increase of the coherent in-plane island size by a factor of ∼4. Modification of the structural quality of the DIP bottom layer leads to a change in structural order in the C60 top layer. In addition, ultraviolet photoelectron spectroscopy data from templated and nontemplated C60 films are discussed. In contrast to other anisotropic organic molecules, for C60 the spectral broadening and density of states of the highest occupied molecular orbital region do not depend significantly on the structural order in the C60 film, which can be rationalized by the isotropic shape of the C60 molecule.

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