Sulfuryl Chloride as an Efficient Initiator for the Metal-Free Aerobic Cross-Dehydrogenative Coupling Reaction of Tertiary Amines
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- Arata Tanoue
- Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan
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- Woo-Jin Yoo
- Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan
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- Shu̅ Kobayashi
- Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan
書誌事項
- 公開日
- 2014-04-11
- 資源種別
- journal article
- DOI
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- 10.1021/ol500661t
- 10.1002/chin.201445169
- 公開者
- American Chemical Society (ACS)
この論文をさがす
説明
A metal-free cross-dehydrogenative (CDC) reaction of tertiary amines was developed using a catalytic amount of sulfuryl chloride (SO2Cl2) under mild aerobic conditions. On the basis of the nature of SO2Cl2, it was assumed that the reagent acts as a radical initiator to induce the metal-free CDC reaction via a radical-initiated autoxidation mechanism.
収録刊行物
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- Organic Letters
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Organic Letters 16 (9), 2346-2349, 2014-04-11
American Chemical Society (ACS)
