Copper-Catalyzed Regioselective Trifluoromethylthiolation of Pyrroles by Trifluoromethanesulfonyl Hypervalent Iodonium Ylide
-
- Zhongyan Huang
- Department of Nanopharmaceutical Sciences, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya466-8555, Japan
-
- Yu-Dong Yang
- Department of Nanopharmaceutical Sciences, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya466-8555, Japan
-
- Etsuko Tokunaga
- Department of Nanopharmaceutical Sciences, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya466-8555, Japan
-
- Norio Shibata
- Department of Nanopharmaceutical Sciences, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya466-8555, Japan
書誌事項
- 公開日
- 2015-02-16
- 資源種別
- journal article
- DOI
-
- 10.1021/ol503616y
- 10.1002/chin.201529150
- 公開者
- American Chemical Society (ACS)
この論文をさがす
説明
The copper-catalyzed trifluoromethylthiolation of pyrroles with a trifluoromethanesulfonyl hypervalent iodonium ylide under mild conditions has been achieved. A broad set of pyrroles could be transformed to the corresponding products in moderate to excellent yields. The reaction mechanism is hypothesized.
収録刊行物
-
- Organic Letters
-
Organic Letters 17 (5), 1094-1097, 2015-02-16
American Chemical Society (ACS)
