Unusual conformational preference of an aromatic secondary urea: solvent-dependent open-closed conformational switching of N,N′-bis(porphyrinyl)urea
書誌事項
- 公開日
- 2013
- 資源種別
- journal article
- DOI
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- 10.1039/c2cc37583d
- 公開者
- Royal Society of Chemistry (RSC)
この論文をさがす
説明
N,N'-Bis(2,3,7,8,12,13,17,18-octaethylporphyrin-5-yl)urea (3) exhibits cis-trans conformational switching depending on the solvent properties, and can adopt the cofacial porphyrin dimer structure under certain conditions. The conformational preference can be switched by electrochemical stimulus.
収録刊行物
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- Chem. Commun.
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Chem. Commun. 49 (23), 2290-2292, 2013
Royal Society of Chemistry (RSC)