A γ-Fluoro β-Acetoxypropyl Sulfonium Salt as an Equivalent of a (Fluoromethyl)vinyl Sulfonium Salt: Reagent for the Facile Synthesis of Monofluoromethylated Cyclopropanes or Aziridines
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- Takeshi Hanamoto
- Department of Chemistry and Applied Chemistry, Saga University
抄録
<jats:p>A β-monofluoromethylated vinyl sulfonium salt, prepared in situ from a precursor γ-fluoro β-acetoxypropyl sulfonium salt under mild basic conditions, reacted with a lvariety of active methylene compounds or a primary sulfone amide under basic conditions to provide the corresponding monofluoromethylated three-membered rings in good-to-excellent yields. This new sulfonium reagent should permit easy access to a variety of important monofluoromethylated organic compounds.</jats:p>
収録刊行物
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- Synlett
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Synlett 29 (18), 2372-2376, 2018-10-01
Georg Thieme Verlag KG
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キーワード
詳細情報 詳細情報について
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- CRID
- 1360004233780024960
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- ISSN
- 14372096
- 09365214
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- データソース種別
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- Crossref
- KAKEN